Any feedback on the use of another structural panel other than plywood, that may help to increase the thermal quality of the floor?
There's nothing I know of that would work for your type of installed heating system. The best method obviously is to have the hydronic tubing embedded in concrete, gypcrete or mud bed.
I think you'll find that the extra plywood layer and Ditra combination will work fine.
On one job I did, the homeowener did not want infloor heating under the tile initially. Needless to say, once it got cooler they wanted a warm floor. The solution was to do a modfied hydronic heat system under the subfloor. This system ran off the existing hot water tank. Let me tell you, that room where the hydronic is, was plenty warm.
Your system would be pretty much the same. I wouldn't worry about it not being warm enough or retaining the heat.