Pick out the tile edging so that it's about 1/16th thicker than the tile. that's 5/16 or 3/8 for the most part. Draw a plumb line with a pencil 1/8th of an inch short of where the edging will go to. Put the edging up against the wall. If there are significant wows in the wall you may have hand bend the edging slightly to make it follow the wall (this part is tricky). Then trowel on a thin layer of thinset just past the line and squish the edging into it. Wipe off any squeeze out on the outside, there should not be any if you do things right. Then leave about a 1/16th grout line and set the tile, troweling more thinset over the edging as you go. I always apply the edging and the tile at the same time, that way you have a chance to move the edging if it's out a bit.
I do sometimes nail on the edging with drywall nails, but that method does not allow for adjustment as you are setting.
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If you lay them right the first time you can walk all over them for the rest of your life.