According to TCNA guidelines, you need 100% silicon for that application.
However, in a Kerdi shower, I grout everything, including changes in plane. I've never had a problem with it cracking. I'm not a fan of any caulk or silicon in a shower due to the fact that it's a maintenance issue down the road, and will eventually harbor mold.
That's just my personal preference, though.
_________________________
The top ten reasons to procrastinate:
1.