Flash is right .... make sure the porcelain tile is freeze/thaw rated and keep a copy of the tile specs (for your own protection). Waterproofing of the deck substrate is a requirement if there are living areas under the decks ... but something to consider even if not.
As you mentioned ... drainage is very important. Try to find a copy of the Tile Council of America handbook .... lots of good information.
As Flash also mentioned .... the 2 part mortar(latex) is the best bond coat for exterior work, but protect it from water while it sets up. Also .... movement joints should also be used where required.
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Harry Dunbar